Corain, B. published the artcileReactivity of cyanogen toward compounds containing active hydrogens at carbon. 5. Cyanoimination reaction of β-keto enolato and Schiff-base complexes of copper and nickel, Application of Copper(II) ethylacetoacetate, the publication is Inorganic Chemistry (1983), 22(19), 2744-9, database is CAplus.
Bis(β-keto enolato)copper(II) complexes and Ni(II) and Cu(II) complexes of the Schiff-base condensation products of 1,3-diketones and diamines react with cyanogen in chlorinated solvents to give cyanoimino-substituted organometallic rings. The reactions occur with high yields and display rates that are strongly affected by the central metal and by the nature of the substituents on the ligands. The new compounds were fully characterized by elemental anal., m.ps., IR and electronic spectroscopy, mass spectra, and thermal anal. I was characterized by x-ray single-crystal anal. The space group is P21/n, Z = 4, with a 19.863(9), b 12.184(8), c 9.739(6) Å, and β 98.4(1)°.
Inorganic Chemistry published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Application of Copper(II) ethylacetoacetate.
Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”