Corain, B. published the artcileCarbon-carbon bond formation upon addition of cyanogen to metal-coordinated β-carbonylenolato and β-ketoiminato ligands, Quality Control of 14284-06-1, the publication is Journal of Organometallic Chemistry (1982), 232(2), C59-C61, database is CAplus.
The addition of C2N2 to a variety of metal-coordinated β-carbonylenolato and β-ketoiminato ligands under ambient conditions affords novel compounds bearing cyanoimino-substituted organometallic rings. The key step of this process is the ready formation of a C-C σ bond upon insertion of C2N2 into the C-H methino bond.
Journal of Organometallic Chemistry published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Quality Control of 14284-06-1.
Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”