Related Products of 14898-67-0. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Ruthenium(III) chloride xhydrate, is researched, Molecular Cl3H2ORu, CAS is 14898-67-0, about Efficient light activation of a [Ru(bpy)(tpy)Cl]+ catalyst by a porphyrin photosensitizer at small driving force. Author is Charalambidis, Georgios; Charisiadis, Asterios; Margiola, Sofia; Coutsolelos, Athanassios; Aukauloo, Ally; Leibl, Winfried; Quaranta, Annamaria.
Light activation of dyads containing porphyrins and a catalytic ruthenium complex having a high oxidation potential (∼1 V vs SCE) is investigated by time-resolved spectroscopy. It is shown that activation of the ruthenium complex occurs through oxidative quenching of the chromophore in the presence of a reversible electron acceptor. Despite the lack of driving force for intramol. electron transfer, an efficient intramol. oxidation of the catalyst is observed, suggesting that porphyrins are attractive chromophores to activate oxidation catalysts throughout the visible spectrum.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”