A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Recommanded Product: 18742-02-4, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 18742-02-4, Name is 2-(2-Bromoethyl)-1,3-dioxolane, molecular formula is C5H9BrO2. In an article, author is Xu, Hui,once mentioned of 18742-02-4.
Construction of 3-Azabicyclo[3.1.0]hexane Backbone by the Reaction of Allenes with Allylamines via Tandem Michael Addition and Copper-Mediated Oxidative Carbanion Cyclization
Main observation and conclusion A facile synthetic method for the construction of 3-azabicyclo[3.1.0]hexane in the presence of copper catalyst system was developed. The reaction proceeds through Michael addition of allylamines with allenes followed by copper-mediated intramolecular oxidative carbanion 5-exo-trig radical cyclization, affording potential biologically active 3-azabicyclo[3.1.0]hexane derivatives in moderate to high yields (42%-85%). [GRAPHICS] .
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Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”