Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. Cuprous thiocyanate,introducing its new discovery. category: copper-catalyst
Syntheses and crystal structure of three novel supramolecular halides/pseudohalides {(DMB)[Cu 2(SCN) 4]}n,{(DMB)[Cu(SCN) 4]}, and {(DMB)[Ag 2(SCN) 4]} n directed by dicationic template possessing C2-symmetry
Three novel hybrid complexes, namely{(DMB)[Cu2(SCN)4]}n (1), {(DMB)[Cu(SCN)4]} (2), and {(DMB)[Ag2(SCN)4]}n (3), have been synthesized via the self-assembly in DMF-methanol system based on multidentate ligand DMB, {DMB = alpha, alpha?- di(3-methylimidozole-1-yl)benzene dichloride}. Single-crystal X-ray diffraction analysis shows 1 and 3 are 1D supramolecules, whereas 2 is mononuclear. Electrostatic interactions between the organic counteranions and inorganic moieties are present and do the contribution to the crystal packing. These compounds have been further characterized by IR spectroscopy and thermostability properties.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”