Downstream synthetic route of [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride

With the complex challenges of chemical substances, we look forward to future research findings about [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride,belong copper-catalyst compound

As a common heterocyclic compound, it belongs to quinuclidine compound,Quinuclidine-4-carboxylic acid hydrochloride,40117-63-3,Molecular formula: C8H14ClNO149,mainly used in chemical industry, its synthesis route is as follows.,578743-87-0

In a glove box, IPrCuCl (224 mg, 0.46 mmol) and potassium tris(1-pyrazolyl)borohydride (127 mg, 0.50 mmol) in THF in a 40 mixture was stirred at room temperature for 3 hours dongan. Filtered through a plug of Celite and the reaction mixture after the evaporation of the solvent under reduced pressure to give product as a white powder IPrCuTp

With the complex challenges of chemical substances, we look forward to future research findings about [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride,belong copper-catalyst compound

Reference£º
Patent; University Of Southern California; Thompson, Mark E; Hamz, Rasya; Durovitch, Peter I; (50 pag.)KR2015/26932; (2015); A;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”