Quality Control of [Ir(dtbbpy)(ppy)2]PF6. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Catalytic Intermolecular Dicarbofunctionalization of Styrenes with CO2 and Radical Precursors. Author is Yatham, Veera Reddy; Shen, Yangyang; Martin, Ruben.
A redox-neutral intermol. dicarbofunctionalization of styrenes e.g., (1-phenylethenyl)benzene with CO2 at atm. pressure and carbon-centered radicals such as CF3SO2Na, CHF2SO2Na, ArCH2BF3K (Ar = Ph, 4-(CH3)3CC6H4), ROC(O)2OCs (R = (CH3)3C, 1-methylcyclohexyl) to afford phenylacetic acids e.g., I was described. This mild protocol results in multiple C-C bond-forming reactions from simple precursors in the absence of stoichiometric reductants, thus exploiting a previously unrecognized opportunity that complements existing catalytic carboxylation events.
《Catalytic Intermolecular Dicarbofunctionalization of Styrenes with CO2 and Radical Precursors》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound([Ir(dtbbpy)(ppy)2]PF6)Quality Control of [Ir(dtbbpy)(ppy)2]PF6.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”