Application of 1111-67-7, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a article£¬once mentioned of 1111-67-7
New oligo-/poly-meric forms for MX:dpex (1:1) complexes (M = Cu I, AgI; X = (pseudo-)halide; dpex = Ph 2E(CH2)xEPh2, E = (P), As; X = 1, 2)
Single-crystal X-ray structural characterizations of MX:dpam (1:1) (‘dpam’ = Ph2AsCH2AsPh2) are reported for MX = AgCl, Br; CuI, CN/Cl (all isomorphous) and AgI, AgSCN, CuSCN arrays, all being of the novel form [(mu-X){M(mu-X)(As-dpam-As?)2M?}] ?, essentially the familiar M(E-dpem-E?) 2M? binuclear array with both ‘bridging’ and (linking) ‘terminal’ (pseudo-)halides involved in the polymer. A different arrangement of bridging and linking entities is found with AgX:dpae (1:1) 2(?|?), X = Br, NCO, ‘dpae’ = Ph2As(CH 2)2AsPh2, now comprising [M(mu-X) 2(As-dpae-As)M] kernels linked by As-dpae-As?, while in the thiocyanate analogue Ag(NCSSCN)Ag units are linked by the dpae ligands into a two-dimensional web. Synthetic procedures for all adducts have been reported. All compounds have been characterized both in solution (1H, 13C, 31P NMR, ESI MS) and in the solid state (IR).
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1111-67-7
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”