Reference of Ruthenium(III) chloride xhydrate. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Ruthenium(III) chloride xhydrate, is researched, Molecular Cl3H2ORu, CAS is 14898-67-0, about Metal-functionalized carbon nanotubes for biomass conversion: base-free highly efficient and recyclable catalysts for aerobic oxidation of 5-hydroxymethylfurfural. Author is Sharma, Poonam; Solanki, Mohit; Sharma, Rakesh K..
In this study, the oxidative conversion of 5-hydroxymethylfurfural into essential chems. on recyclable metal (Pt, Pd, Ru, Co, & Ni)- supported catalysts is reported. While most of the catalytic reactions require a base as an additive, this current study provided a base-free environmentally benign heterogeneous catalytic system. The reactions were performed on various M/CNT catalysts. As a support, CNT played an important role in the reaction mechanism. These catalysts showed a high activity for the base free oxidation of HMF under air in aqueous media. The CNT-supported Pt, Pd, and Ru catalysts were found to be more selective towards FDCA (>97%) compared to Ni and Co for DFF (>96%). The conversion and selectivity of the products were determined using NMR and HPLC. The (1 wt%) M/CNT catalysts were prepared via solution processing and were characterized using BET, XRD, TEM, TGA, FTIR, and XPS.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”