The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Ruthenium(III) chloride xhydrate, is researched, Molecular Cl3H2ORu, CAS is 14898-67-0, about TNT Sensor: Stern-Volmer Analysis of Luminescence Quenching of Ruthenium Bipyridine, the main research direction is ruthenium bipyridine luminescence quenching trinitrotoluene sensor Stern Volmer analysis.Computed Properties of Cl3H2ORu.
TNT is both toxic and explosive, and therefore the detection of TNT represents an environmental and a security concern. Dogs are often used for detection, but other methods are needed. This laboratory investigates a ruthenium bipyridine ([Ru(bpy)3]2+) luminescence-based trinitrotoluene (TNT) sensor. Students will synthesize [Ru(bpy)3]2+, investigate sensors, and consider possible mechanistic pathways of quenching. Students are unlikely to have analyzed luminescence quenching data previously and using TNT shows how important the technique is for problems like national security, environmental contamination, and landmine deactivation. The content of the lab is ideal for upper-level laboratories, when students have the foundational coursework to appreciate the interdisciplinary nature of chem. as the experiment integrates inorganic, anal., and phys. chem.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”