Let¡¯s face it, organic chemistry can seem difficult to learn. SDS of cas: 1111-67-7. Especially from a beginner¡¯s point of view. Like SDS of cas: 1111-67-7, Name is Cuprous thiocyanate. In a document type is Article, introducing its new discovery.
Organocatalyzed Asymmetric alpha-Thiocyanation of Oxindoles: Synthesis of Chiral Tertiary 3-Thiocyanatoxindoles
An enantioselective thiocyanation of oxindoles has been developed for the first time using a bifunctional cinchona-derived organo-catalyst and N-thiocyanatophthalimide as the electrophilic thiocyanation source in the presence of 2-naphthol as the additive. Various enantioenriched 3,3?-disubstituted oxindoles with SCN-containing quaternary carbon stereocenters were synthesized under mild conditions in high yields (up to 99%) and good enantioselectivities (up to 6:94 er).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.SDS of cas: 1111-67-7. In my other articles, you can also check out more blogs about 1111-67-7
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”