Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. Formula: CCuNS, Name is Cuprous thiocyanate, Formula: CCuNS, molecular formula is CCuNS. In a article，once mentioned of Formula: CCuNS
Two different 1D-chains in the structures of the copper(I) coordination polymers based on bidentate Schiff-base building units and thiocyanate anions as bridging ligands
The reaction of the bidentate Schiff-base ligands (3,4,5-MeO-ba)2en (L1) and (4-Me-ba)2en (L2) with Cu(SCN) in CH3CN yielded two copper(I) coordination polymers [Cu(L1)(SCN)]n (1) and [Cu(L2)(SCN)]n (2), which have been characterized by elemental analyses, IR- and 1H NMR-spectroscopy, and X-ray crystallography. The non-centrosymmetric structures of both Cu(I) complexes consist of an one-dimensional polymeric chain in which copper(I) ions are bridged by two thiocyanate groups bonding in an end-to-end fashion. The Cu(I)?Cu(I) separation is 5.604 A in 1 and 5.706 A in 2.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”