Let’s face it, organic chemistry can seem difficult to learn. Computed Properties of CCuNS. Especially from a beginner’s point of view. Like Computed Properties of CCuNS, Name is Cuprous thiocyanate. In a document type is Article, introducing its new discovery.
Organocuprate cross-coupling: The central role of the copper(III) intermediate and the importance of the copper(I) precursor
(Chemical Equation Presented) CuIII in focus: The key intermediate in copper-mediated cross-coupling reactions has long been believed to be a “copper-(III) intermediate”. Investigation of reactions of a variety of methyl Gilman reagents Me2CuLi·LiX with Etl using rapid-injection NMR spectroscopy conditions reveals a number of formally Cu III tetra-coordinate square-planar intermediates (see scheme) with a surprising range of stabilities.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 1111-67-7
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”