Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, molecular formula is C6H12O3. In an article, author is Wang, Xiaoguang,once mentioned of 14347-78-5, Product Details of 14347-78-5.
Molecular H2O promoted catalytic bicarbonate reduction with methanol into formate over Pd0.5Cu0.5/C under mild hydrothermal conditions
Direct reduction of bicarbonate, a typical product of CO2 captured in alkaline solution, into value-added organics is one promising way to achieve a simplified and green CO2 capture and utilization process. In this work, a new strategy of bicarbonate reduction coupled with methanol oxidation into a dual formation of formate under mild hydrothermal conditions is reported. A 68% formate production efficiency based on the reductant methanol and nearly 100% selectivity of formate were obtained via a Pd0.5Cu0.5/C catalyst at 180 degrees C. An operando hydrothermal ATR-FTIR study proved that the bicarbonate was reduced by the in situ generated hydrogen from methanol, which was stepwise oxidized to formaldehyde and formic acid. Notably, DFT calculations and a qNMR study of the C-13 and H-2 (D) isotopic labelling revealed that H2O molecules not only supplied the hydrogen for bicarbonate reduction but also acted as an indispensable promoter to enhance the catalytic performance of Pd0.5Cu0.5/C for methanol activation.
If you¡¯re interested in learning more about 14347-78-5. The above is the message from the blog manager. Product Details of 14347-78-5.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”