Using tetramethylammonium hydroxide electrolyte to inhibit corrosion of Mg-based amorphous alloy anodes: A route for promotion energy density of Ni-MH battery was written by Huang, Jianling;Liao, ChengWei;Wang, Hui;Zhao, YuJun;Ouyang, Liuzhang;Liu, Jiangwen;Zhu, Min. And the article was included in Journal of Alloys and Compounds in 2022.Synthetic Route of CuH2O2 This article mentions the following:
Mg-based alloy anodes suffer from severe corrosion in conventional electrolytes (KOH solution) and this substantially obstructs the cycle life, which is a great challenge for using them in the Ni-MH battery. Herein, a high concentration tetramethylammonium hydroxide (TMAH) aqueous electrolyte with a special hydrate structure is explored and enables excellent cycle stability and high capacity for Mg-based alloy anodes. In this electrolyte, the Mg0.4Ti0.1Ni0.5 alloy anode delivers a maximum discharge capacity of 466 mAh g-1, and maintains 210 mAh g-1 after 100 cycles owing to the reduced corrosion rate, which are much better than that in 6 M KOH electrolyte, being 425 mAh g-1 and 69 mAh g-1, resp. Furthermore, by in-situ forming Cu coating on the Mg0.4Ti0.1Ni0.5 electrode surface during charging process with the adding 0.01 M of Cu(OH)2 in TMAH electrolyte, the corrosion of the electrode is further suppressed and the reversible capacity can reach 313 mAh g-1 after 100 cycles. The high conducting Cu coating can also increase the rate capability of the electrode by promoting the charge transfer. Thus, using TMAH electrolytes provides a new approach to promote the electrochem. performances of Ni-MH batteries with Mg-based alloy anodes. In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2Synthetic Route of CuH2O2).
Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. Copper catalyst has received great attention owing to the low toxicity and low cost. Due to these characteristics, copper nanoparticles have generated a great deal of interest especially in the field of catalysis. Synthetic Route of CuH2O2
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”