The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. COA of Formula: CCuNSIn an article, once mentioned the new application about 1111-67-7.
Three pillared-layered inorganic-organic hybrid polymers with efficient luminescence
Three pillared-layered inorganic-organic hybrid polymers, namely, [Cu2(4,4?-Hbpt)(SCN)2]n (1), [Cd(4,4?-Hbpt)(SCN)2]n (2), and [Cd(4,4?-Hbpt)(SCN)2·CH3CN]n (3) were synthesized via layer diffusion methods. In all three complexes, there exist 2-D neutral wave-like d10 metal thiocyanate layers (for 1, [Cu2(SCN)2]n, and for 2 and 3, [Cd(SCN)2]n) with (4, 4) topology, which are further connected by bidentate 4,4?-Hbpt ligands to form 3-D structures with the primitive cubic topology. The results of photoluminescence and thermogravimetric analyses indicate that the three complexes are good candidates as luminescent materials. This paper provides a strategy to synthesize a novel family of pillared-layered inorganic-organic hybrid polymers constructed with layered d10 metal thiocyanate layers and conjugated organic spacers at the molecular engineering level, as well as the discovery of new patterns of crystallization at the crystal engineering level.
Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 1111-67-7 is helpful to your research.
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”