Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, name: Cuprous thiocyanate, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. name: Cuprous thiocyanateIn an article, authors is Tang, Zheng-Zhen, once mentioned the new application about name: Cuprous thiocyanate.
Inorganic CuSCN and organic tetrathiafulvalene derivatives (TTFs) have been exploited as hole-transport materials (HTM) in hybrid perovskite solar cells. To develop new HTM, we herein report two hybrid materials incorporating redox-active TTFs with CuSCN framework (TTFs-CuSCN). Single-crystal analysis showed that compound [Cu2(py-TTF-py)(SCN)2] (1) is three-dimensional (3D) and compound [Cu(py-TTF-py)(SCN)] (2) is two-dimensional (2D) (py-TTF-py = 2,6-bis(4?-pyridyl)tetrathiafulvalene). There are covalent coordination interactions between CuSCN and py-TTF-py and short S···S contacts between the py-TTF-py ligands for both compounds. Besides, C···S contacts exist between py-TTF-py ligands of the neighboring 2D networks in 2, which facilitate the charge transfer and supply efficient multidimensional pathways for carrier migration. As a result, 2 presented better semiconductor performance in comparison with that of 1. The performance of 2 related to the HTMs could be significantly improved by modulating the electronic state of the TTFs-CuSCN framework via oxidative doping. The iodine-doped 2D material (2-I2) gives the most excellent conductivity and carrier mobility, which might be a potential new HTM.
Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. A catalyst, does not appear in the overall stoichiometry of the reaction it catalyzes. you can also check out more blogs about HPLC of Formula: C8H12B2F8N4Pd!, name: Cuprous thiocyanate
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”