Name is Copper(I) bromide, as a common heterocyclic compound, it belongs to copper-catalyst compound, and cas is 7787-70-4, its synthesis route is as follows.
General procedure: [CuBr(CNR)3] (1-4). Any one of the isocyanides CNR (R=Xyl, 2-Cl-6-MeC6H3, 2-Naphtyl, Cy) (3.1mmol) was added to a suspension of CuBr (143mg, 1.0mmol) in chloroform (5mL) and the reaction mixture was stirred at RT for 1h. The solvent was removed in vacuo and the product was recrystallized by slow concentration of a CH2Cl2/hexane solution at RT to give colorless (1, 2, and 4) or orange (3) crystalline solid. (0027) [CuBr(CNXyl)3] (1). Yield 530mg, 99%. Anal. Calc. for C27H27N3BrCu: C, 60.39; H, 5.07; N, 7.83. Found: C, 59.88; H, 4.89; N, 7.70%. HRESI+-MS, m/z: 325.0756 ([M-(XylNC)2]+, calcd 325.0760). IR spectrum in KBr, selected bands, cm-1: 2136 s nu(C?N). 1H NMR in CDCl3, delta: 2.49 (s, 6H, CH3), 7.11 (d, J 7.6Hz, 2H, aryl) 7.23 (d, J 7.6Hz, 1H, aryl). 13C{1H} NMR in CDCl3, delta: 18.95 (CH3), 127.92, 129.33, 135.49 (aryl).
7787-70-4, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,7787-70-4 ,Copper(I) bromide, other downstream synthetic routes, hurry up and to see
Reference£º
Article; Melekhova, Anna A.; Novikov, Alexander S.; Luzyanin, Konstantin V.; Bokach, Nadezhda A.; Starova, Galina L.; Gurzhiy, Vladislav V.; Kukushkin, Vadim Yu.; Inorganica Chimica Acta; vol. 434; (2015); p. 31 – 36;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”