Kijima, Ichiro’s team published research in Nippon Kagaku Kaishi in | CAS: 14284-06-1

Nippon Kagaku Kaishi published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Computed Properties of 14284-06-1.

Kijima, Ichiro published the artcileReaction of tin(II) chloride with bis(β-diketonato)copper complexes, Computed Properties of 14284-06-1, the publication is Nippon Kagaku Kaishi (1987), 171-3, database is CAplus.

SnCl2 reacts with [Cu(acac)2] (Hacac = acetylacetone) in a 2:1 molar ratio to give an oxidative addition product [SnCl2(acac)2] and a partial replaced product [SnCl(acac)]. Similar results were also noted in the reaction between SnCl2 and [Cu(bdm)2] (Hdbm = dibenzoylmethane). However, only the corresponding oxidative addition product, [SnCl2(etac)2], was isolated from the reaction of SnCl2 with [Cu(etac)2] (Hetac = Et acetoacetate) under the same reaction conditions. The equimolar reaction of SnCl2 with [Cu(acac)2] afforded the oxidative addition product and [Sn(acac)2], together with the formation of a trace amount of [SnCl(acac)] as the reaction products. The mechanism for the formation of these products is discussed.

Nippon Kagaku Kaishi published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Computed Properties of 14284-06-1.

Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”