The author of 《Modulating the surface segregation of PdCuRu nanocrystals for enhanced all-pH hydrogen evolution electrocatalysis》 were Li, Menggang; Luo, Mingchuan; Xia, Zhonghong; Yang, Yong; Huang, Yarong; Wu, Dong; Sun, Yingjun; Li, Chunji; Chao, Yuguang; Yang, Wenxiu; Yang, Weiwei; Yu, Yongsheng; Guo, Shaojun. And the article was published in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2019. Quality Control of Bis(acetylacetone)copper The author mentioned the following in the article:
Core-shell architecture coupled with rational surface engineering constitutes an efficient strategy for promoting electrocatalysis on multimetallic nanocrystals via the optimization of composition, facets and coordination environment. Here, by leveraging controlled surface segregation, we realize core-shell formation with systematic tuning of surface composition on well-defined PdCuRu nanocrystals. When applied for the hydrogen evolution reaction (HER), we established a direct correlation between surface composition and activity. In particular, PdCuRu catalysts with a Pd-rich surface achieved an overpotential of 31 mV at a c.d. of 10 mA cm-2 and a low Tafel slope of 52 mV dec-1 in an alk. electrolyte, considerably enhanced relative to control PdCuRu/C catalysts with other surface compositions and even exceeding those of state-of-the-art Pt/C. Similar trends were also observed in both neutral and acid electrolytes. We deduce that, in this catalytic system, the enhanced electrocatalysis originates from the strain effect rather than the bifunctional mechanism. The present study builds a bridge between surface engineering and HER performance, and opens up new material designs for surface Pd-rich core-shell nanostructures for the purpose of improving HER catalytic activity and stability at all pH values. In addition to this study using Bis(acetylacetone)copper, there are many other studies that have used Bis(acetylacetone)copper(cas: 13395-16-9Quality Control of Bis(acetylacetone)copper) was used in this study.
Bis(acetylacetone)copper(cas: 13395-16-9) is used as PVC stabilizer, and curing agents for epoxy resins, acrylic adhesives and silicone rubbers. It is also used as solvents, lubricant additives, paint drier, and pesticides.Quality Control of Bis(acetylacetone)copper
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”