《Observation of field-induced single-ion magnet behavior in a mononuclear DyIII complex by co-crystallization of a square-planar CuII complex》 was published in Inorganica Chimica Acta in 2020. These research results belong to Li, Xi-Li; Li, Junfeng; Wang, Ailing; Liu, Cai-Ming; Cui, Minghui; Zhang, Yi-Quan. Recommanded Product: 13395-16-9 The article mentions the following:
Employing Cu(acac)2 to react with Dy(hfac)3(H2O)2 (where acac- = acetylacetonate and hfac- = 1,1,1,5,5,5-hexafluoroacetylacetonate), the first true 3d-4f metal-complex cocrystal with the composition of [Cu(acac)2·Dy(hfac)3(H2O)2] that only consists of reactants, was acquired and structurally characterized. Magnetic investigations revealed that the 4f conformer Dy(hfac)3(H2O)2 does not show slow magnetic relaxation behavior even under an applied dc field of 2000 Oe down to 1.9 K, while the obtained 3d-4f cocrystal displays evident slow magnetic relaxation behavior associated with single-ion magnet (SIM) characteristic under the same dc field. This phenomenon is further supported and elucidated by the results of theor. calculations together with the analyses of their crystal structures. Thus our results first indicate that 3d-4f co-crystallization technique is a useful tool for improving the magnetic performance of lanthanide complexes. In addition to this study using Bis(acetylacetone)copper, there are many other studies that have used Bis(acetylacetone)copper(cas: 13395-16-9Recommanded Product: 13395-16-9) was used in this study.
Bis(acetylacetone)copper(cas: 13395-16-9) catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. Recommanded Product: 13395-16-9
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”