Trinitro-orcinolate and Trinitro-resorcinate – Sensitivity Trends in Nitroaromatic Energetic Materials was written by M. J. Endrass, Simon;Neuer, Andreas;Klapotke, Thomas M.;Stierstorfer, Jorg. And the article was included in ChemistrySelect in 2022.HPLC of Formula: 20427-59-2 This article mentions the following:
5-Methyl-2,4,6-trinitrobenzene-1,3-diol (trinitro-orcinol, H2TNO) as a close structural relative to the well-known energetic materials trinitroresorcinol (styphnic acid) and trinitrotoluene (TNT) is prepared in high purity and analyzed concerning its vapor pressure using the transpiration method. Several energetic coordination compounds (ECCs) of its resp. anion were produced and compared with structurally close styphnate complexes to give an insight into physiochem. trends of the ECC. The synthesized compounds were further analyzed by elemental anal., IR spectroscopy, DTA and low temperature X-ray diffraction anal. To classify the reported compounds among the energetic materials, they were tested for their sensitivities towards mech. stimuli such as impact, friction and electrostatic discharge as well as their behavior towards flame. In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2HPLC of Formula: 20427-59-2).
Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. The applications of Copper-based nanoparticles have received great attention due to the earth-abundant, inexpensive and low toxicity. The copper-mediated C-C, C-O, C-N, and C-S bond formation is a part of one oldest reaction, emphasizing the Ullmann cross-coupling reaction.HPLC of Formula: 20427-59-2
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”