Kaihovirta, Nikolai; Longo, Giulia; Gil-Escrig, Lidon; Bolink, Henk J.; Edman, Ludvig published an article about the compound: [Ir(dtbbpy)(ppy)2]PF6( cas:676525-77-2,SMILESS:[F-][P+5]([F-])([F-])([F-])([F-])[F-].CC(C)(C1=CC=[N]([Ir+3]23([C-]4=CC=CC=C4C5=CC=CC=[N]25)([C-]6=CC=CC=C6C7=CC=CC=[N]37)[N]8=CC=C(C(C)(C)C)C=C98)C9=C1)C ).Related Products of 676525-77-2. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:676525-77-2) through the article.
The quant. and qual. effects are reported of self-absorption in light-emitting electrochem. cells (LECs) based on ionic transition metal complexes (iTMCs), as measured in-situ during elec. driving. A yellow-emitting iTMC-LEC comprising an active material thickness of 95 nm suffers a 4% loss of the emission intensity to self-absorption, whereas the same type of device but with a larger active-material thickness of 1 μm will lose a significant 40% of the light intensity. The LEC-specific effect of doping-induced self-absorption can result in a drift of the emission spectrum with time for iTMC-LECs, but note that the overall magnitude of doping-induced self-absorption is much smaller than for conjugated-polymer LECs. (c) 2015 American Institute of Physics.
Different reactions of this compound([Ir(dtbbpy)(ppy)2]PF6)Related Products of 676525-77-2 require different conditions, so the reaction conditions are very important.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”