Copper(II) trifluoromethanesulfonate (cas: 34946-82-2) belongs to copper catalysts. The transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents has turned up as an exceedingly robust synthetic tool. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Quality Control of Copper(II) trifluoromethanesulfonate
Understanding the effect of structural changes on slow magnetic relaxation in mononuclear octahedral copper(II) complexes was written by Marcinkowski, Dawid;Adamski, Ariel;Kubicki, Maciej;Consiglio, Giuseppe;Patroniak, Violetta;Slusarski, Tomasz;Acikgoz, Muhammed;Szeliga, Daria;Vadra, Nahir;Karbowiak, Miroslaw;Stefaniuk, Ireneusz;Rudowicz, Czeslaw;Gorczynski, Adam;Korabik, Maria. And the article was included in Dalton Transactions in 2022.Quality Control of Copper(II) trifluoromethanesulfonate This article mentions the following:
Current advances in mol. magnetism are aimed at the construction of mol. nanomagnets and spin qubits for their use as high-d. data storage materials and quantum computers. Mononuclear coordination compounds with low spin values of S = 1/2 are excellent candidates for this endeavour, but knowledge of their construction via rational design is limited. This particularly applies to the single copper(II) spin center, having been only recently demonstrated to exhibit slow relaxation of magnetization in the appropriate octahedral environment. The authors thus prepared a unique organic scaffold that would allow one to gain in-depth insight into how purposeful structural differences affect the slow magnetic relaxation in monometallic, transition metal complexes. As a proof-of-principle, one can construct two, structurally very similar complexes with isolated Cu(II) ions in an octahedral ligand environment, the magnetic properties of which differ significantly. The differences in structural symmetry effects and in magnetic relaxation are corroborated with exptl. techniques and theor. approaches, showing how symmetry distortions and crystal packing affect the relaxation behavior in these isolated Cu(II) systems. The unique organic platform can be efficiently used for the construction of various transition-metal ion systems in the future, effectively providing a model system for investigation of magnetic relaxation via targeted structural distortions. In the experiment, the researchers used many compounds, for example, Copper(II) trifluoromethanesulfonate (cas: 34946-82-2Quality Control of Copper(II) trifluoromethanesulfonate).
Copper(II) trifluoromethanesulfonate (cas: 34946-82-2) belongs to copper catalysts. The transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents has turned up as an exceedingly robust synthetic tool. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Quality Control of Copper(II) trifluoromethanesulfonate
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”