Navarro, Yolanda et al. published their research in Dalton Transactions in 2021 | CAS: 14781-45-4

copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. The evolution of transition metal catalysts has attained a stage of civilization that authorizes for an extensive scope of chemical bonds formation partners to be combined efficiently. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Formula: C10H2CuF12O4

Synthesis, crystal structures and magnetic properties of a P-stereogenic ortho-(4-amino-tempo)phosphinic amide radical and its CuII complex was written by Navarro, Yolanda;Guedes, Guilherme P.;del Aguila-Sanchez, Miguel A.;Iglesias, Maria Jose;Lloret, Francisco;Lopez-Ortiz, Fernando. And the article was included in Dalton Transactions in 2021.Formula: C10H2CuF12O4 This article mentions the following:

The synthesis of phosphinic amides containing one 4-amino-TEMPO substituent at the ortho position was achieved through copper(I) catalyzed cross-coupling reactions of ortho-iodophosphinic amides with 4-amino-TEMPO. The method was extended to the preparation of the first example of a P-stereogenic ortho-(4-amino-tempo)phosphinic amide radical 10. The reaction of 10 with Cu(hfac)2 afforded the P-stereogenic CuII complex 19. The crystal structure of both chiral compounds is reported. The mol. structure of 10 consists of a supramol. zigzag chain formed by intermol. hydrogen bonds between the NH group of the phosphinic amide moiety and the nitroxide oxygen atom. In complex 19, the ligand acts as a bridge between two CuII ions coordinated to the oxygen atoms of the P=O and N-O· groups giving a polymeric helicate chain in which the metal ions exist in a distorted octahedral geometry. The magnetic behavior of ligand 10 was characterized by very weak intermol. antiferromagnetic interactions, whereas ferro- and anti-ferromagnetic interactions are present in complex 19. In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4Formula: C10H2CuF12O4).

copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. The evolution of transition metal catalysts has attained a stage of civilization that authorizes for an extensive scope of chemical bonds formation partners to be combined efficiently. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Formula: C10H2CuF12O4

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”