Chemistry, like all the natural sciences, Recommanded Product: (R)-4-Methyl-1,3-dioxolan-2-one, begins with the direct observation of nature¡ª in this case, of matter.16606-55-6, Name is (R)-4-Methyl-1,3-dioxolan-2-one, SMILES is O=C1OC[C@@H](C)O1, belongs to copper-catalyst compound. In a document, author is Song, Hui, introduce the new discover.
Copper-oxygen synergistic electronic reconstruction on g-C3N4 for efficient non-radical catalysis for peroxydisulfate and peroxymonosulfate
Due to the selectivity and environmental tolerance of non-radical reaction reactions, they have emerged as a promising way to treat special water bodies. Herein, we proposed a new non-radical reaction system that used a Cu and O co-doped g-C3N4 catalyst (CuO-CN) activated by peroxydisulfate (PDS) or peroxymonosulfate (PMS). In CuO-CN, Cu and O atoms were introduced into the structure of graphitic carbon nitride (g-C3N4) in an innovative configuration, resulting in a differentiated charge distribution around the Cu and O centres. The PDS/CuO-CN and PMS/CuO-CN systems could selectively degrade organic pollutants (e.g., bisphenol A, BPA) over a wide pH range (3-9), and the maximum BPA removal could reach 99%. For the PDS/CuO-CN system, the mechanism was hypothesized to involve the effective removal of BPA via electron transfer, and the PMS/CuO-CN system exploited the synergistic effect of singlet oxygen (O-1(2)) and electron transfer. This study describes a novel process for effective PMS or PDS activation by CuO-CN to efficiently degrade organic pollutants via a non-radical pathway.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 16606-55-6. Recommanded Product: (R)-4-Methyl-1,3-dioxolan-2-one.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”