Application of 1111-67-7, In an article, published in an article,authors is Sakae, Ryosuke, once mentioned the application of Application of 1111-67-7, Name is Cuprous thiocyanate,molecular formula is CCuNS, is a conventional compound. this article was the specific content is as follows.
Copper-catalyzed stereoselective aminoboration of bicyclic alkenes
A copper-catalyzed aminoboration of bicyclic alkenes, including oxa- and azabenzonorbornadienes, has been developed. With this method, amine and boron moieties are simultaneously introduced at an olefin with exo selectivity. Subsequent stereospecific transformations of the boryl group can provide oxygen- and nitrogen-rich cyclic molecules with motifs that may be found in natural products or pharmaceutically active compounds. Moreover, a catalytic asymmetric variant of this transformation was realized by using a copper complex with a chiral bisphosphine ligand, namely (R,R)-Ph-BPE.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”