Application of 676525-77-2. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis. Author is Miyazawa, Kazuki; Koike, Takashi; Akita, Munetaka.
A simple and regiospecific aminohydroxylation of olefins by photoredox catalysis has been developed. N-protected 1-aminopyridinium salts are the key compounds and serve as amidyl radical precursors by the action of Ir photocatalysts, fac-[Ir(ppy)3] and [Ir(ppy)2(dtbbpy)](PF6) (ppy=2-pyridylphenyl, dtbbpy=4,4′-di-tert-butyl-2,2′-bipyridine). The present photocatalytic system allows for synthesis of vicinal aminoalc. derivatives from olefins with various functional groups under mild reaction conditions with easy handling.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”