14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, molecular formula is C6H12O3, belongs to copper-catalyst compound, is a common compound. In a patnet, author is Yang, Anzhou, once mentioned the new application about 14347-78-5, Safety of (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol.
Modulating Hydroxyl-Rich Interfaces on Nickel-Copper Double Hydroxide Nanotyres to Pre-activate Alkaline Ammonia Oxidation Reactivity
The surface hydroxyl groups of NixCu1-x(OH)(2) play a crucial role in governing their conversion efficiency into NixCu1-xOx(OH)(2-x) during the electro-chemical pre-activation process, thus affecting the integral ammonia oxidation reaction (AOR) reactivity. Herein, the rational design of hierarchical porous NiCu double hydroxide nanotyres (NiCu DHTs) was reported for the first time by considering hydroxyl-rich interfaces to promote pre-activation efficiency and intrinsic structural superiority (i.e., annulus, porosity) to accelerate AOR kinetics. A systematic investigation of the structure-function relationship was conducted by manipulating a series of NiCu DHs with tunable intercalations and morphologies. Remarkably, the NiCu DHTs exhibit superior AOR activity (onset potential of 1.31 V with 7.52 mA cm(-2) at 1.5 V) and high ammonia sensitivity (detection limit of 9 mu m), manifesting one of the best non-noble metal AOR electrocatalysts and electro-analytical electrodetectors. This work deepens the understanding of the crucial role of surface hydroxyl groups on determining the catalytic performance in alkaline medium.
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Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”