Hu, Dawei; Wang, Linghua; Li, Pengfei published an article about the compound: [Ir(dtbbpy)(ppy)2]PF6( cas:676525-77-2,SMILESS:[F-][P+5]([F-])([F-])([F-])([F-])[F-].CC(C)(C1=CC=[N]([Ir+3]23([C-]4=CC=CC=C4C5=CC=CC=[N]25)([C-]6=CC=CC=C6C7=CC=CC=[N]37)[N]8=CC=C(C(C)(C)C)C=C98)C9=C1)C ).SDS of cas: 676525-77-2. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:676525-77-2) through the article.
The conventional methods for preparing alkyl boronates often necessitate anhydrous and demanding reaction conditions. Herein, a new, operationally simple decarboxylative borylation reaction of readily available aliphatic acid derivatives under additive-free visible-light photoredox conditions in nonanhydrous solvents was described. Primary and secondary alkyl boronates or tetrafluoroborates with various functional groups were prepared accordingly. A catalytic cycle involving alkyl radical reaction with base-activated diboron species is proposed.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”