Perez, Yolanda published the artcileCopper-containing catalysts for solvent-free selective oxidation of benzyl alcohol, Computed Properties of 14284-06-1, the publication is Journal of Molecular Catalysis A: Chemical (2012), 45-56, database is CAplus.
Two different methods for the preparation of copper-containing catalysts have been described. Copper (II) ethylacetoacetate or copper (II) nitrate metallic precursors have been immobilized onto previously organofunctionalized MCM-41 material with N 4-(3-(triethoxysilyl)propyl)pyrimidine-2,4,6-triamine (DAPyPTS) compound The amino hybrid materials have been prepared by using both post-synthesis and co-condensation methods. In addition, the immobilization has been performed using organic and aqueous media. The catalysts have been characterized using X-ray diffraction (XRD), N2 adsorption-desorption, inductively coupled plasma-at. emission spectroscopy (ICP-AES), scanning electron microscope (SEM) with energy-dispersive X-ray (EDX), elemental anal., 1H, 13C and 28Si MAS NMR, FT-IR and DRUV-vis spectroscopy. Copper-containing catalysts have been tested in the benzyl alc. oxidation with TBHP and H2O2 as oxidants and under solventless conditions. High selective (97%) to benzaldehyde was achieved using TBHP as oxidant and the copper (II) ethylacetoacetate immobilized onto organofunctionalized MCM-41 as catalyst under solventless conditions.
Journal of Molecular Catalysis A: Chemical published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Computed Properties of 14284-06-1.
Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”