Synthetic Route of 1111-67-7, In an article, published in an article,authors is Van Der Vlugt, Jarl Ivar, once mentioned the application of Synthetic Route of 1111-67-7, Name is Cuprous thiocyanate,molecular formula is CCuNS, is a conventional compound. this article was the specific content is as follows.
T-shaped cationic CuI complexes with hemilabile PNP-type ligands
The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6- bis[(diphenylphosphino)methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”