Xuan, Jun; Feng, Zhu-Jia; Duan, Shu-Wen; Xiao, Wen-Jing published an article about the compound: [Ir(dtbbpy)(ppy)2]PF6( cas:676525-77-2,SMILESS:[F-][P+5]([F-])([F-])([F-])([F-])[F-].CC(C)(C1=CC=[N]([Ir+3]23([C-]4=CC=CC=C4C5=CC=CC=[N]25)([C-]6=CC=CC=C6C7=CC=CC=[N]37)[N]8=CC=C(C(C)(C)C)C=C98)C9=C1)C ).COA of Formula: C40H40F6IrN4P. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:676525-77-2) through the article.
A novel and efficient construction of isoquino[2,1-a][3,1]oxazine and isoquino[2,1-a]pyrimidine frameworks has been realized by means of visible light photocatalytic reactions using air as the oxidant at room temperature This strategy offers a direct and rapid access to two kinds of biol. important fused heterocycles in good to excellent yields.
Different reactions of this compound([Ir(dtbbpy)(ppy)2]PF6)COA of Formula: C40H40F6IrN4P require different conditions, so the reaction conditions are very important.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”