Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. We’ll be discussing some of the latest developments in chemical about CAS: Computed Properties of C10H16CuO4, Name is Bis(acetylacetone)copper, belongs to copper-catalyst compound, is a common compound. Computed Properties of C10H16CuO4In an article, authors is Jain, Suman L., once mentioned the new application about Computed Properties of C10H16CuO4.
The reactions of a series of 1,2,3,4-tetrahydropyridin-2-ones (1) with diazoacetates (2) in the presence of copper-bronze catalyst yielded exclusively 3-oxo-2-azabicyclo [4.1.0] heptanes (3 and 4) in excellent yields with high exo-selectivity. Tetrahydropyridin-2-ones (1) with N-alkyl substituents were found to be more reactive than N-aryl substitutents. Among the various copper catalysts studied, copper(II) triflate was found to be the best catalyst while rhodium chloride, ruthenium chloride did not catalyze the reaction. The application of ultrasonic radiation enhanced the reaction rate and allowed the reactions to be conducted at room temperature.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”