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Copper(I) pseudohalide complexes with 4,6-dimethylpyrimidine-2(1H)-thione and triphenylphosphane as ligands. The X-ray crystal structures of [Cu(N3)(dmpymtH)(PPh3)2] and [Cu(NCS)(dmpymtH)(PPh3)2]
The preparation of mixed-ligand copper (I) coordination compounds containing pseudohalides (azide and thiocyanate), 4,6-dimethylpyrimidine-2(1H)-thione (dmpymtH), and triphenylphosphane is described. The crystalline and molecular structure of [Cu(N3)(dmpymth)(PPh3)2] (2) and [Cu(NCS)(dmpymtH)(PPh3)]2 (3) have been determined by X-ray diffraction methods. The copper atom has a tetra-coordinate CuNP2S chromophore with distorted tetrahedral coordination in both complexes. Vibrational and 1H, 13C, 31P NMR spectra of the complexes are discussed and related to the structures
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”