Related Products of 1111-67-7, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 1111-67-7, molcular formula is CCuNS, introducing its new discovery.
METAL PSEUDOHALIDE COMPLEXES, VI. COPPER(I) AZIDE COMPLEXES WITH SOME PYRIDINE DERIVATIVES, EXAMPLES OF END-TO-END BRIDGING AZIDES
A series of stable, coloured and diamagnetic copper(I) azido complexes of the type CuLnN2, where L=3-, and 4-CHO-py, 2-, 3-, and 4-COCH3-py, 2-, 3-, and 4-COOCH3-py, 2-, 3-, and 4-COOC2H5-py, 2-COC6H5-py and 4-CN-py, n=1 or 2, in addition to some new CuL2(NCS) complexes have been isolated and characterized.All these carbonyl ligands act as monodentate ones in the isolated complexes.IR results suggest that the azide groups in the isolated azido complexes act as bridging ligands through the two end nitrogen atoms.CuL2(NCS) complexes have almost distorted tetrahedral geometry through bridging thiocyanate groups.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”