In 2022,Smurova, L. A.; Kartasheva, Z. S. published an article in Russian Chemical Bulletin. The title of the article was 《Features of catalytic activity of binary systems based on d-metal compounds and cetyltrimethylammonium bromide for tert-butyl hydroperoxide decomposition as an example》.HPLC of Formula: 13395-16-9 The author mentioned the following in the article:
Binary systems based on the Cu, Ni, and Co complexes with various ligands and cationic surfactant cetyltrimethylammonium bromide (CTAB) were prepared The catalytic activity of these systems in the decomposition of tert-Bu hydroperoxide (TBHP) was studied. A specific feature of the CuII-CTAB and NiII-CTAB catalytic systems is that in terms of the decomposition rate of the peroxide bond they are superior to their individual components. The highest efficiency was detected when the copper complexes were used in the binary systems. The CTAB additives combined with Co(acac)2 exert an inhibition effect on the catalytic activity of cobalt, while the CTAB additives exert no effect in the case of other CoL2 compounds Assumptions about the mechanism of action of the binary systems were advanced. After reading the article, we found that the author used Bis(acetylacetone)copper(cas: 13395-16-9HPLC of Formula: 13395-16-9)
Bis(acetylacetone)copper(cas: 13395-16-9) catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. HPLC of Formula: 13395-16-9
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”