Synthetic Route of 1111-67-7, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a Article£¬once mentioned of 1111-67-7
Synthesis, spectral studies of cobalt(II) tetrathiocyanoto dicuperate(I) complexes with some acylhydrazones and their antimicrobial activity
Cobalt(II) complexes of the type Co[Cu(NCS)2]2 ? L, where L is acetophenonebenzoylhydrazone (Abh), acetophenoneisonicotinoylhydrazone (Ainh), acetophenonesalicyloylhydrazone (Ash), acetophenoneanthraniloylhydrazone (Aah), p- hydroxyacetophenonebenzoylhydrazone (Phabh), p- hydroxyacetophenoneisonicotinoylhydrazone (Phainh), p- hydroxyacetophenonesalicyloylhydrazone (Phash), and p- hydroxyacetophenoneanthraniloylhydrazone (Phaah) were synthesized and characterized by elemental analyses, molar conductance, magnetic moments, electronic and IR spectra, and X-ray diffraction studies. The complexes are insoluble in common organic solvents and are non-electrolytes. These complexes are coordinated through the >C=O and >C=N groups of the hydrazone ligands. The magnetic moments and electronic spectra suggest a spin-free octahedral geometry around Co(II). The X-ray diffraction parameters (a, b, c) for Co[Cu(SCN)2]2 ? Ainh and Co[Cu(SCN)2] 2 ? Phabh correspond to orthorhombic and tetragonal crystal lattices, respectively. The complexes show a fair antifungal and antibacterial activity against a number of fungi and bacteria. The activity increases with increasing concentration of the compounds.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”