Reference of 1111-67-7, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 1111-67-7, Cuprous thiocyanate, introducing its new discovery.
A thiocyanato-bridged copper(i) cubane complex and its application in palladium-catalyzed Sonogashira coupling of aryl halides
Reaction of copper(i) thiocyanate with 1,1?-bis(di-tert- butylphosphino) ferrocene (dtbpf) in a 2:1 molar ratio in DCM-MeOH (50:50 V/V) afforded a tetranuclear copper(i) complex [Cu4(mu3-SCN) 4(kappa1-P,P-dtbpf)2] (1) with a cubane-like structure. Complex 1 was shown to be an efficient catalyst in comparison to CuI in the Sonogashira reaction. The coupling products were obtained in high yields by using Pd loadings of 0.2 mol% as well as complex-1 of 0.1 mol%.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1111-67-7, help many people in the next few years.Reference of 1111-67-7
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”