In heterogeneous catalysis, the catalyst is in a different phase from the reactants. name: Cuprous thiocyanate, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 1111-67-7, name is Cuprous thiocyanate. In an article£¬Which mentioned a new discovery about 1111-67-7
2-Picolinic acid and benzoic acid from di-2-pyridyl ketone and acetophenone: A case of two copper catalysed Baeyer-Villiger rearrangements?
The synthesis and crystal structure elucidation of two novel polymeric copper(II) complexes has led us to propose a mechanism for the formation of 2-picolinic acid (pic) from di-2-pyridyl ketone (dpk) and benzoic acid from acetophenone. During studies into the interaction of copper ions with the dpk-acetophenone system, two complexes Na2(NCS)2(H 2O)[Cu(pic)2] (1) and Na2(H2O) 2[Cu(pic)2(NCS)2] (2) which contain pic coordinated to copper were isolated. The occurrence of (1) and (2) has led us to consider the Baeyer-Villiger rearrangement as a possible mechanism for the formation of (1) and (2).
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”