The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Aluminum triquinolin-8-olate( cas:2085-33-8 ) is researched.Synthetic Route of C27H18AlN3O3.Zhong, Haoxiang; Zhao, Yangzhi; Zhang, Ting; Liu, Gao published the article 《Controlled Lithium Deposition on Alq3 Coated Substrate**》 about this compound( cas:2085-33-8 ) in Batteries & Supercaps. Keywords: lithium tris 8hydroxy quinolinatoaluminum copper coating spectrum. Let’s learn more about this compound (cas:2085-33-8).
High theor. charge capacity (3,860 mAh g-1) and low redox potential (-3.04 V vs. standard hydrogen electrode) make lithium metal a promising anode for next-generation high energy d. battery. However, the practical implementation of Li-metal anode is still elusive due to poor coulombic efficiency and cycling performance as well as safety concerns caused by lithium dendrite formation and poor compatibility of liquid electrolyte with lithium. In this work, we developed a strategy to control lithium deposition and growth by using surface modified electrodes coated by a conductive chelate compound tris-(8-hydroxyquinoline) aluminum (Alq3) onto copper current collector. As a result, Alq3 exhibits good conductivity and electrochem. stability verified by cyclic voltammetry test. The Alq3 can modulate lithium metal growth on Cu surface, in addition, it demonstrates morphol. control of deposited lithium by tuning variables such as c.d. and coating thickness. Optimal cycling stability and stable coulombic efficiency over 300 cycles are observed on the LiAlq3/Cu cell at 50 nm coating thickness – an evidence shows controlled lithium deposition by this simple but effective surface modified electrode.
There is still a lot of research devoted to this compound(SMILES：[O-]C1=C2N=CC=CC2=CC=C1.[O-]C3=C4N=CC=CC4=CC=C3.[O-]C5=C6N=CC=CC6=CC=C5.[Al+3])Synthetic Route of C27H18AlN3O3, and with the development of science, more effects of this compound(2085-33-8) can be discovered.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”