In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Safety of Cuprous thiocyanate, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 1111-67-7, name is Cuprous thiocyanate. In an article£¬Which mentioned a new discovery about 1111-67-7
Copper-Catalyzed Silylation of C(sp3)-H Bonds Adjacent to Amide Nitrogen Atoms
A copper-catalyzed C-Si bond formation between N-halogenated amides and Si-B reagents is described. This oxidative coupling enables the silylation of C(sp3)-H bonds alpha to an amide nitrogen atom. The utility of the new method is demonstrated for sulfonamides, and N-chlorination with tBuOCl and C-H silylation employing CuSCN/4,4?-dimethoxy-2,2?-bipyridine as catalyst can be performed without purification of the N-Cl intermediate.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”