The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, SMILES is OC[C@H]1OC(C)(C)OC1, in an article , author is Kazmierczak, Kamila, once mentioned of 14347-78-5, COA of Formula: C6H12O3.
Activity of heterogeneous supported Cu and Ru catalysts in acceptor-less alcohol dehydrogenation
Acceptor-less alcohol dehydrogenation reaction allows the co-production of added-value carbonyl compounds and H-2 from alcohols. Focusing on supported Ru and Cu catalysts, we evaluated the support effect on the dehydrogenation of 2-octanol and 1-octanol and identified the side products as resulting from aldolisation coupling. The most active and selective catalysts were then tested on the aliphatic vicinal-diol octan-1,2-diol and the highest conversion was reached using Cu/ZrO2 (60%) with a high selectivity (94%) towards 1-hydroxy-2-octanone.
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Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”