Related Products of 1111-67-7, Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 1111-67-7, Name is Cuprous thiocyanate,introducing its new discovery.
Thiocyanato complexes of the coinage metals: Synthesis and crystal structures of the polymeric pyridine complexes [AgxCuy(SCN)x+y(py)z]
From solutions of CuSCN or AgSCN in pyridine, several pyridine complexes of the thiocyanates with varying compositions and crystal structures were isolated depending on the reaction conditions. In CuSCN and in the orthorhombic modification of AgSCN the SCN- anions co-ordinate to four metal atoms as 1,1,1,3-mu4 bridges, whereas the degree of bridging decreases with increasing amounts of pyridine in the polymeric complexes [Cu(SCN)(py)z] and [Ag(SCN)(py)z] (z = 1 or 2). The distorted tetrahedral co-ordination of the metal atoms is preserved by co-ordination of pyridine ligands. Especially in the heteronuclear complexes [AgCu(SCN)2(py)4], [AgCu(SCN)2(py)3] and [Ag2Cu(SCN)3(py)3], interesting variants of structures result from the different possible modes of co-ordination of the SCN- ligand and from the preferred co-ordination of the “soft” S atoms to the “soft” Ag+ ions as defined by Pearson’s hard and soft acid and base principle.
We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 1111-67-7, and how the biochemistry of the body works.Related Products of 1111-67-7
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”