Formula: Cl3H2ORu. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Ruthenium(III) chloride xhydrate, is researched, Molecular Cl3H2ORu, CAS is 14898-67-0, about Amphiphilic polypyridyl ruthenium complexes: Synthesis, characterization and aggregation studies. Author is Bhand, Sujit; Lande, Dipali N.; Pereira, Eulalia; Gejji, Shridhar P.; Weyhermuller, Thomas; Chakravarty, Debamitra; Puranik, Vedavati G.; Salunke-Gawali, Sunita.
Synthesis and characterization of five amphiphilic ruthenium(II) complexes of the type [Ru(Cn)3].(PF6)2 (Cn = 4,4′-dialkyl-2,2′-bipyridine, n = 5 (4,4′-dipentyl), 6 (4,4′-dihexyl), 7 (4,4′-diheptyl), 8 (4,4′-dioctyl), 9 (4,4′-dinonyl)) were studied. Single crystal x-ray structures of 4,4′-dipentyl-2,2′-bipyridine (C5), 4,4′-dioctyl-2,2′-bipyridine (C8) ligands and [Ru(C5)3](PF6)2 complex are elucidated. Structural inferences are corroborated through the d. functional theory. Mol. aggregations in these systems in aqueous and non-aqueous media have further been analyzed from FESEM experiments
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”