The author of 《Thermodynamic modeling of the solubility of acetylacetonate-type metal precursors in supercritical carbon dioxide using the PC-SAFT equation of state》 were Ushiki, Ikuo; Sato, Yoshiyuki; Takishima, Shigeki; Inomata, Hiroshi. And the article was published in Journal of Chemical Engineering of Japan in 2019. Related Products of 13395-16-9 The author mentioned the following in the article:
Thermodn. modeling of the solubilities of various acetylacetonate-type metal precursors in supercritical carbon dioxide was performed using the PC-SAFT (perturbed-chain statistical associating fluid theory) equation of state. Pure component parameters for the metal precursors (segment number, segment diameter, and dispersion energy) were determined by fitting to solubility data obtained from the literature. The PC-SAFT equation of state could correlate the literature data over wide temperature and pressure ranges for various precursors. The pure component PC-SAFT parameters obtained from these correlations were found to vary systematically with changes in the properties of the metal precursors, such as the molar masses of the precursors and of the metal centers, which could be generalized based on the phys. meaning of each parameter. The generalized PC-SAFT parameters could reproduce the solubilities of the metal precursors in supercritical carbon dioxide to within 30% average relative deviation under almost all conditions, especially at temperature below 393 K. The results came from multiple reactions, including the reaction of Bis(acetylacetone)copper(cas: 13395-16-9Related Products of 13395-16-9)
Bis(acetylacetone)copper(cas: 13395-16-9) catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. Related Products of 13395-16-9
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”