《Edge Enrichment of Ultrathin 2D PdPtCu Trimetallic Nanostructures Effectuates Top-Ranked Ethanol Electrooxidation》 was written by Wang, Wei; Zhang, Xue; Zhang, Yuhui; Chen, Xiaowei; Ye, Jinyu; Chen, Jiayu; Lyu, Zixi; Chen, Xuejiao; Kuang, Qin; Xie, Shuifen; Xie, Zhaoxiong. Name: Bis(acetylacetone)copper And the article was included in Nano Letters in 2020. The article conveys some information:
Atomic edge sites on two-dimensional (2D) nanomaterials display striking catalytic behavior, whereas edge engineering for 2-dimensional metal nanocatalysts remains an insurmountable challenge. Here the authors advance a 1-pot synthesis of ultrathin 2-dimensional PdPtCu trimetallic nanosheets and nanorings with escalating low-coordinated edge proportions from 11.74% and 23.11% to 45.85% as cutting-edge EtOH oxidation reaction (EOR) electrocatalysts. This in situ edge enrichment hinges on a competitive surface capping and etching strategy with integrated manipulation of the reaction kinetics. Electrocatalysis tests demystify an edge-relied EOR performance, where the edge-richest 9.0 nm-Pd61Pt22Cu17 nanorings attain an exceptional activity (12.42 A mg-1Pt+Pd, 20.2 times that of com. Pt/C) with substantially improved durability. Molecularly mechanistic studies certify that the unsaturated edge sites on these 2-dimensional catalysts prevail, triggering the C-C bond scission and succeeding CO removal to facilitate a 12-electron-transferring EOR process. This study introduces the metal-edge-driven concept and enables the edge sites on 2-dimensional multimetallic nanocatalysts technique to design versatile heterocatalysts. After reading the article, we found that the author used Bis(acetylacetone)copper(cas: 13395-16-9Name: Bis(acetylacetone)copper)
Bis(acetylacetone)copper(cas: 13395-16-9) catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. Name: Bis(acetylacetone)copper
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”