Zhang, Fanyu; Zhang, Bingxing; Feng, Jiaqi; Tan, Xiuniang; Liu, Lei; Liu, Lifei; Han, Buxing; Zheng, Lirong; Zhang, Jing; Tai, Jing; Zhang, Jianling published an article about the compound: Ruthenium(III) chloride xhydrate( cas:14898-67-0,SMILESS:Cl[Ru](Cl)Cl.[H]O[H] ).Product Details of 14898-67-0. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:14898-67-0) through the article.
The application of metal-organic frameworks (MOFs) in catalysis is largely restricted by their intrinsic properties, thus the development of modified MOFs is promising for improving the activities. Here, the authors propose the formation of Ru-coordinated MOF with a hierarchically meso- and microporous structure by a supercritical fluid route. Such a photocatalyst has the preferable electronic structure, improved visible-light adsorption ability, and high porosity for facilitating mass transport. Owing to these combined advantages, the as-synthesized Ru-coordinated MOF catalyst exhibits outstanding photocatalytic activity for H production, which is much higher than those of the pure MOF and the Ru nanoparticle-loaded MOF. This study opens up new opportunity for improving the catalytic performances of MOFs by modifying their microstructures through a supercritical fluid route.
Different reactions of this compound(Ruthenium(III) chloride xhydrate)Product Details of 14898-67-0 require different conditions, so the reaction conditions are very important.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”