Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 2568-25-4, Name is Benzaldehyde Propylene Glycol Acetal, molecular formula is C10H12O2. In an article, author is Wan, Xiao,once mentioned of 2568-25-4, Name: Benzaldehyde Propylene Glycol Acetal.
Regio- and enantioselective ring-opening reaction of vinylcyclopropanes with indoles under cooperative catalysis
The title reaction has been established under the cooperative bimetallic catalysis of iridium and copper catalysts, which afforded indole C3-allylation products with branched selectivity in moderate yields (up to 78%) and good enantioselectivities (up to 97 : 3 er). This reaction not only represents the first catalytic asymmetric ring-opening reaction of vinylcyclopropanes with C3-unsubstituted indoles, but also has provided an atom-economic and straightforward method for the synthesis of C3-allylic indoles with high regio- and enantioselectivity.
Interested yet? Keep reading other articles of 2568-25-4, you can contact me at any time and look forward to more communication. Name: Benzaldehyde Propylene Glycol Acetal.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”