HPLC of Formula: 676525-77-2. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about A Radical Cascade Enabling Collective Syntheses of Natural Products. Author is Wang, Xiaobei; Xia, Dongliang; Qin, Wenfang; Zhou, Ruijie; Zhou, Xiaohan; Zhou, Qilong; Liu, Wentao; Dai, Xiang; Wang, Huijing; Wang, Shuqing; Tan, Ling; Zhang, Dan; Song, Hao; Liu, Xiao-Yu; Qin, Yong.
An efficient photocatalytic radical cascade method that enabled access to libraries of chiral and multiple-ring-fused tetrahydrocarbolinones such as I [R = Me, CH2CN, Bn, etc.], II [R1 = (CH2)2CN, (CH2)2Ac, CH=CHAc, etc.] and III [R2 = CHO, Ac, CN, etc.; R3 = H, OMe; EWG = Ac, CO2Me, C(O)CH2OTBS] was reported. The radical cascade could controllably introduced complexity and functionality into products with excellent chemo-, regio- and diastereoselectivity. The power of this distinct method was demonstrated by the efficient synthesis of 33 monoterpenoid indole alkaloids belonging to four families. Promisingly, the radical cascade was green, water insensitive and readily scalable.
This literature about this compound(676525-77-2)HPLC of Formula: 676525-77-2has given us a lot of inspiration, and I hope that the research on this compound([Ir(dtbbpy)(ppy)2]PF6) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”